Application and Research Progress of Dihydroxylammonium 5,5’-bistetrazole-1,1’-diolate(TKX-50)in Explosives & Propellants

ZHANG Kun,WANG Jian,WANG Xiao-feng,FENG Xiao-jun

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Chinese Journal of Explosives & Propellants ›› 2022, Vol. 45 ›› Issue (1) : 20-29. DOI: 10.14077/j.issn.1007-7812.202104023

Application and Research Progress of Dihydroxylammonium 5,5’-bistetrazole-1,1’-diolate(TKX-50)in Explosives & Propellants

  • ZHANG Kun1,WANG Jian2,WANG Xiao-feng1,FENG Xiao-jun1
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Abstract

The synthesis and preparation, crystal properties and mechanical properties of dihydroxylammonium-5,5'-bistetrazole-1,1'-diolate(TKX-50)compound are introduced, and the current research status on performance improvement, compatibility, energy, and safety applications are summarized. The difference between TKX-50 and traditional neutral nitramine explosives were compared. The TKX-50 is an ionic salt structure without the traditional energetic group —NO2, and the energy release method is by breaking high-energy bonds instead of redox reactions, which brings the calculated energy characteristics such as enthalpy of formation, detonation heat, and combustion heat have a large difference with the test results. Finally, the application advantages and existing problems of TKX-50 were summarized, and the future development direction and research focus were prospected. It is pointed out that the energy characteristics of nitrogen-rich energetic ionic salts represented by TKX-50 should be fully exploited, and the special properties of such materials should be utilized to expand their application in the field of propellants and explosives.

Key words

applied chemistry / dihydroxylammonium5,5'-bistetrazole-1,1'-diolate / TKX-50 / physicochemical properties / compatibility / nitrogen-rich energetic ionic salts / HATO

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ZHANG Kun,WANG Jian,WANG Xiao-feng,FENG Xiao-jun. Application and Research Progress of Dihydroxylammonium 5,5’-bistetrazole-1,1’-diolate(TKX-50)in Explosives & Propellants. Chinese Journal of Explosives & Propellants. 2022, 45(1): 20-29 https://doi.org/10.14077/j.issn.1007-7812.202104023

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