Thermal Decomposition Kinetics of 3-Amino-4-nitrosofurazan

ZHANG Ming-yan1, CHEN Li-ping1, WU Wen-qian1, WANG Shun-yao2,CHEN Wang-hua1

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Chinese Journal of Explosives & Propellants ›› 2020, Vol. 43 ›› Issue (5) : 516-520. DOI: 10.14077/j.issn.1007-7812.201908017

Thermal Decomposition Kinetics of 3-Amino-4-nitrosofurazan

  • ZHANG Ming-yan1, CHEN Li-ping1, WU Wen-qian1, WANG Shun-yao2,CHEN Wang-hua1
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Abstract

To study the thermal stability of 3-amino-4-nitrosofurazan(ANSF), the thermal decomposition characteristics of ANSF were studied by differential scanning calorimetry(DSC)at different heating rates under isothermal conditions. The decomposition reaction kinetic parameters were calculated by model-free method and model-based method. The dynamic test results show that the onset temperature of ANSF is very low and the heat release is very large. The average specific heat release is up to 2945J/g. The isothermal DSC curves show that the decomposition of ANSF is autocatalytic both at liquid and solid phase. The activition energy obtained by model-free method changes obviously with the conversion rate, indicating that the decomposition reaction is complex and can't be described by a single step mechanism. The apparent activation energy of the initial stage and autocatalytic stage calculated by simplified Benito-Perez model are 114.75kJ/mol and 109.02kJ/mol, respectively. ANSF has poor thermal stability and the decomposition is autocatalytic both at solid and liquid phase with low activation energy.

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physical chemistry / 3-amino-4-nitrosofurazan / ANSF / autocatalytic / thermal decomposition / model-based kinetics

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ZHANG Ming-yan1, CHEN Li-ping1, WU Wen-qian1, WANG Shun-yao2,CHEN Wang-hua1. Thermal Decomposition Kinetics of 3-Amino-4-nitrosofurazan. Chinese Journal of Explosives & Propellants. 2020, 43(5): 516-520 https://doi.org/10.14077/j.issn.1007-7812.201908017

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