本文研究了含硝基的茋的合成方法。Shipp反应不适用于所用的硝基化合物。三硝基间甲基苯胺和三硝基二甲苯通过Knoevenagel反应与芳醛缩合成茋，后者还可形成二（苯乙烯基）苯化合物。由间硝基苯甲醛与间硝基苯乙酸通过Peikin反应合成3，3ˊ-二硝基茋，得率比用Meerwein反应高一倍。
Abstract
The synthesis of stilbsnes containing the nitro group were studied. The Shipp process is not applicable for the nitro-compounds used. Trinitro-m-toludine and trinitro-m-xylene were condensed with aroma?tic aldehydes to form stilbenes. Distyrylbenzenes containing the nitro group may be formed from trinitro-m-xylene. The procedure for the synthesis of 3，3ˊ-dinitrostilbene from m-nitro-benzaldeliyde and m-nitrophenylacetic acid via the Perkin reaction was found to be superior to that through the Meerwein reaction.
关键词
茋 /
二（苯乙烯基）苯 /
多硝基化合物 /
合成
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Key words
stilbene /
distyrylbenzene /
polynitro compound /
synthesis
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参考文献
〔1〕Shipp, K. G. , J. Org. Cliem.，29，1964, 260.
〔2〕Buckley, E. ； Eyerard, J. E. & Wells, C. H. J. , Chem. and Trd. , London, 1978, 124.
〔3〕Buckley, E. ； Houiellebecq, T. F. & Wells, C. H. J.，Proplnt. Explos. Pyrotech,，9 , 1984, 135.
〔4〕Fyfe, C. A. ；Malkiewich, C. D. j Damji, S. W. H. & Norris, A. R. , JACS, 98, 1976，6983.
〔5〕LˊEcuyer, P. & Turcotte, F. , Can. J . Res. , 25.B, 1947，375
〔6〕IˊEcuyer, P.; Turcotte，F.； Giguere, J.； Oliver, C. A. & Roberge, P. , Can. J. Res. , 26B， 1948, 70.
〔7〕Pfeiffer5 P.& Sergiewskaja, S.，Ber.，44, 1911，1107.
〔8〕Smith, W. , Org. Synth. , coll. Vol. Ⅳ 1963, 730.
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脚注
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