为改善含纳米铝粉HTPB复合推进剂和PBX炸药的工艺性能，研究了纳米Al与HTPB悬浮液的流变性能，用RS300流变仪研究了混合时间、混合比例、纳米Al粒度、表面活性剂等因素对悬浮液流变性能的影响。结果表明，在50℃恒温50h，HTPB的表观黏度值变化小，其表观黏度值变化不影响悬浮液的流变性能。随着纳米Al与HTPB质量比的增大和纳米铝粉粒度的减小，悬浮液的黏度系数减小，剪切速率指数增大，假塑性逐渐增强，悬浮液的流变性能变差。表面活性剂能显著降低纳米Al/HTPB悬浮液的初始混合表观黏度和屈服值。

Starting from diaminofurazan(DAF),5,5-[methanedinitramino-bis(1,2,5oxadiazol-4,3-diyl)]bis[1H-[1,2,3]triazolo[4,5-c]-[1,2,5]oxadiazolium]-bis(innersalt)(MNOTO)was synthesized by oxidation with Caro′s acid, reductionwith Zn dust， cyclization, condensation reaction andnitration with condense nitrate acid/acetic anhydride in 32.7% yield .Thestructures of intermediates and MNOTO were characterized by elemental analyses,IR and NMR. Condense nitrate acid with acetic anhydride was employed in thenitration of 5,5’-[Methanediamino-bis(1,2,5oxadiazol-4,3-diyl)]bis[1H-[1,2,3]triazolo[4,5-c][1,2,5]oxadiazolium]-bis(innersalt)(MAOTO).Theeffects of reaction temperature，reaction time and molarratio of condense nitrate acid to acetic anhydride on the conversion of MAOTOto MNOTO were studied. The optimal reaction conditions obtained were：reaction temperature, 15-20℃;reactiontime,5h;the molar ratio of condense nitrate acid to acetic anhydride,1.5∶1.