火炸药组分迁移研究进展

王宏霞，顾 妍，付 腾，于思龙，王芳芳，刘文亮，杜姣姣，张林军

火炸药学报 ›› 2024, Vol. 47 ›› Issue (11) : 978-992.

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  • 主管：中国科学技术协会

    主编：魏 卫

    ISSN 1007-7812

    　

  • 主办：中国兵工学会与中国兵器工业第204研究所共同

    出版：《火炸药学报》 编辑部

    CN 61-1310/TJ

《火炸药学报》1978年创刊，国内外公开发行。是由中国科协主管、中国兵工学会与中国兵器工业第二〇四研究所共同主办的学术刊物, 是我国创刊最早的火炸药技术专业期刊。
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火炸药学报 ›› 2024, Vol. 47 ›› Issue (11) : 978-992. DOI: 10.14077/j.issn.1007-7812.202401013

火炸药组分迁移研究进展

  • 王宏霞1,顾 妍1,付 腾2,于思龙1,王芳芳1,刘文亮1,杜姣姣1,张林军1
作者信息 +

Research Progress on Ingredient Migration of Explosives and Propellants

  • WANG Hong-xia1, GU Yan1, FU Teng2, YU Si-long1, WANG Fang-fang1, LIU Wen-liang1, DU Jiao-jiao1, ZHANG Lin-jun1
Author information +
文章历史 +

摘要

针对推进剂、发射药和炸药中组分迁移的机理、迁移规律的特性表征、迁移的影响因素以及迁移的抑制,介绍了以浓度梯度和极性作用为迁移驱动力的浓度扩散理论与极性作用理论,归纳了基于先进分析技术和迁移动力学的组分迁移量及迁移能力表征方法,阐述了温度、分子间相互作用、交联密度、位阻、结构等因素对组分迁移的影响,总结了化学合成法、材料改性法、添加剂法等迁移抑制方法,提出了建立快速、无损的组分迁移表征方法、完善迁移模型以及新型抗迁移组分的合成等发展方向。附

Abstract

Aiming at the mechanism, regularity characterization, influence factors and inhibition of ingredient migration in propellants, gun propellants and explosives, the ingredient migration theories which are mainly driven by concentration gradient and polarity action were introduced. The characterization methods of migration ingredients amount and migration ability based on advanced analytical techniques and migration kinetics were summarized. The effects of temperature, intermolecular interactions, crosslinking density, steric hindrance, structure, and other factors on ingredient migration were elaborated. The migration inhibition methods including chemical synthesis, material modification, and additive methods were discussed. The development directions of establishing rapid and non-destructive characterization methods of ingredient migration, improving migration models and synthesizing new ingredients with high anti-migration performance were proposed.Attached with 79 references.

关键词

分析化学 / 火炸药 / 组分迁移 / 迁移机理 / 表征方法 / 影响因素 / 迁移抑制

Key words

analytical chemistry / explosives and propellants / ingredient migration / migration mechanism / characterization methods / influence factors / migration inhibition

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王宏霞，顾 妍，付 腾，于思龙，王芳芳，刘文亮，杜姣姣，张林军. 火炸药组分迁移研究进展. 火炸药学报. 2024, 47(11): 978-992 https://doi.org/10.14077/j.issn.1007-7812.202401013
WANG Hong-xia, GU Yan, FU Teng, YU Si-long, WANG Fang-fang, LIU Wen-liang, DU Jiao-jiao, ZHANG Lin-jun. Research Progress on Ingredient Migration of Explosives and Propellants. Chinese Journal of Explosives & Propellants. 2024, 47(11): 978-992 https://doi.org/10.14077/j.issn.1007-7812.202401013
中图分类号： TJ55    TQ560   

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