单原子催化剂的催化效果及其作为固体推进剂燃烧催化剂的应用前景分析

薛 妍，曲文刚，刘所恩，高红旭，牛诗尧，付青山，王 艳，陈锦芳，赵凤起

火炸药学报 ›› 2023, Vol. 46 ›› Issue (4) : 275-284.

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  • 主管：中国科学技术协会

    主编：魏 卫

    ISSN 1007-7812

    　

  • 主办：中国兵工学会与中国兵器工业第204研究所共同

    出版：《火炸药学报》 编辑部

    CN 61-1310/TJ

《火炸药学报》1978年创刊，国内外公开发行。是由中国科协主管、中国兵工学会与中国兵器工业第二〇四研究所共同主办的学术刊物, 是我国创刊最早的火炸药技术专业期刊。
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火炸药学报 ›› 2023, Vol. 46 ›› Issue (4) : 275-284. DOI: 10.14077/j.issn.1007-7812.202205005

单原子催化剂的催化效果及其作为固体推进剂燃烧催化剂的应用前景分析

  • 薛 妍1,2,曲文刚1,刘所恩2,高红旭1,牛诗尧1,付青山1,王 艳3,陈锦芳2,赵凤起1
作者信息 +

The Catalytic Effect of Single Atom Catalysts and Its Application Prospect in Solid Propellant

  • XUE Yan1,2,QU Wen-gang1,LIU Suo-en2,GAO Hong-xu1,NIU Shi-yao1,FU Qing-shan1,WANG Yan3,CHEN Jin-fang2,ZHAO Feng-qi1
Author information +
文章历史 +

摘要

随着先进火箭与导弹技术进一步发展,现有燃烧催化剂已经无法满足推进剂技术进一步向着高能、燃气清洁以及燃烧可控方向发展的需求,体现在催化效率不够高、催化选择性差以及缺乏催化模型3个方面。而单原子催化剂具有高催化活性和选择性、高稳定性和100% 原子利用率等显著优势,将单原子催化剂引入推进剂燃烧催化领域有望突破固体推进剂燃烧性能高效、精准调控这一瓶颈问题。主要介绍了单原子催化剂的制备方法和表征技术,分析了单原子燃烧催化剂在固体推进剂领域的作用效果,指出了单原子催化剂的优势所在,进一步结合现有燃烧催化剂研究经验,预测了单原子燃烧催化剂发展趋势,分别从微观结构多样化设计与构建方面丰富单原子燃烧催化剂体系以及从分子层面认知催化反应机理,明确固体推进剂单原子催化燃烧机制。附

Abstract

With the further development of advanced rocket and missile technology, existing combustion catalysts have been unable to meet the needs of propellant technology, which is further developing towards high energy, cleaned combustion gas and controlled combustion, which reflected in three aspects: low catalytic efficiency, poor catalytic selectivity and lacking of catalytic model. Single-atom catalysts have significant advantages such as high catalytic activity, selectivity, high stability and 100% atom utilization rate. The introduction of single-atom catalysts into the field of propellant combustion catalysis is expected to break through the bottleneck problem of high efficient and precise control of solid propellant combustion performance. The preparation method and characterization technique of single-atom catalysts were introduced, the effects of single-atom combustion catalysts in the field of solid propellant were analyzed, and the advantages of single-atom catalysts were pointed out. A reasonable prediction of the development trend of single-atom combustion catalysts combining the existing research experience of combustion catalysts were further made: enriching the single-atom combustion catalyst system from the aspects of diversified design and construction of microstructure and understanding the catalytic reaction mechanism from the molecular level, to clarify the single-atom catalytic combustion mechanism of solid propellant. 63 References were attched.

关键词

物理化学 / 固体推进剂 / 单原子催化剂 / 燃烧催化剂 / 热分解 / 应用前景

Key words

physical chemistry / solid propellant / single atom catalysts / combustion catalyst / thermal decomposition / application prospect

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薛 妍，曲文刚，刘所恩，高红旭，牛诗尧，付青山，王 艳，陈锦芳，赵凤起. 单原子催化剂的催化效果及其作为固体推进剂燃烧催化剂的应用前景分析. 火炸药学报. 2023, 46(4): 275-284 https://doi.org/10.14077/j.issn.1007-7812.202205005
XUE Yan,QU Wen-gang,LIU Suo-en,GAO Hong-xu,NIU Shi-yao,FU Qing-shan,WANG Yan,CHEN Jin-fang,ZHAO Feng-qi. The Catalytic Effect of Single Atom Catalysts and Its Application Prospect in Solid Propellant. Chinese Journal of Explosives & Propellants. 2023, 46(4): 275-284 https://doi.org/10.14077/j.issn.1007-7812.202205005
中图分类号： TJ55    V512   

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