Synthesis of 2-methoxy-35-dinitryl-6-azidepyrazine

LIU Yao-peng;CHEN Hua-xiong;CHEN Shu-sen;JIN Shao-hua

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  • Sponsored by: China Association for Science and Technology (CAST)

    Editor-In-Chief: Xu Yida

    ISSN 1000-1093

    　

  • Hosted By: China Ordnance Society

    Published By: Acta Armamentarii

    CN 11-2176/TJ

Acta Armamentarii, a Chinese monthly journal, was first published in 1979. The journal is supervised by China Association for Science and Technology, sponsored by China Ordnance Society，and edited and published by Editorial Board of Acta Armamentarii. The Journal is included in all important domestic databases，and also collected by Engineering Index (EI, USA), Chemical Abstracts (CA, USA), Science Abstracts (SA, UK）, Abstract Journal (AJ, Russia), and Current Bibliography on Science and Technology(CBST).Acta Armamentarii has been selected into the journal Of Ordnance Science and Technology (Weapons Industry) Field Of High Quality Scientific and Technological Periodical Classification Catalogue (2022 edition), ranking T1, and the journal of Automotive Engineering Field of High Quality Scientific and technological Periodical classification Catalogue, ranking T2.
Acta Armamentarii ›› 2010, Vol. 31 ›› Issue (10) : 1357-1362. DOI: 10.3969/j.issn.1000-1093.2010.10.014
Paper

Synthesis of 2-methoxy-35-dinitryl-6-azidepyrazine

  • LIU Yao-peng1, CHEN Hua-xiong2, CHEN Shu-sen2, JIN Shao-hua2
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Abstract

MDNAP is a precursor for novel energetic compounds. 2-methoxy-6-chlorin pyrazine (MCP) was first synthesized from raw material 2,6-dichlorin pyrazine by substituting chlorine with methoxyl with a yield of 81%.2-methoxy-3,5-dinitryl-6-chlorin pyrazine (MDNCP) was obtained by the nitration of MCP with mixed nitric and sulfuric acids under facile conditions with a yield of 75%.2-methoxy -3,5-dinitryl-6-azide pyrazine (MDNAP) was synthesized from MDNCP by the zaide substitution of MDNCP with a yield of 60%. Therein, all the intermediates were characterized by IR, H1 NMR, ESI-MS and EI-MS.

Key words

organic chemistry / 2-methoxy-3,5-dinitryl-6-azidepyrazine / pyrazine / azide substitution / nitration

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LIU Yao-peng, CHEN Hua-xiong, CHEN Shu-sen, JIN Shao-hua. Synthesis of 2-methoxy-35-dinitryl-6-azidepyrazine. Acta Armamentarii. 2010, 31(10): 1357-1362 https://doi.org/10.3969/j.issn.1000-1093.2010.10.014

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