On the Mechanism of Thermal Decomposition of N，Nˊ-Dinitrom-e thylenediamine

Jiang Delin;Liu Ziru;Wu Chengyun

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  • Sponsored by: China Association for Science and Technology (CAST)

    Editor-In-Chief: Xu Yida

    ISSN 1000-1093

    　

  • Hosted By: China Ordnance Society

    Published By: Acta Armamentarii

    CN 11-2176/TJ

Acta Armamentarii, a Chinese monthly journal, was first published in 1979. The journal is supervised by China Association for Science and Technology, sponsored by China Ordnance Society，and edited and published by Editorial Board of Acta Armamentarii. The Journal is included in all important domestic databases，and also collected by Engineering Index (EI, USA), Chemical Abstracts (CA, USA), Science Abstracts (SA, UK）, Abstract Journal (AJ, Russia), and Current Bibliography on Science and Technology(CBST).Acta Armamentarii has been selected into the journal Of Ordnance Science and Technology (Weapons Industry) Field Of High Quality Scientific and Technological Periodical Classification Catalogue (2022 edition), ranking T1, and the journal of Automotive Engineering Field of High Quality Scientific and technological Periodical classification Catalogue, ranking T2.
Acta Armamentarii ›› 1987, Vol. 8 ›› Issue (1) : 19-29. DOI: 10.3969/j.issn.1000-1093.1987.01.003
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On the Mechanism of Thermal Decomposition of N，Nˊ-Dinitrom-e thylenediamine

  • Jiang Delin、Liu Ziru、Wu Chengyun
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Abstract

The thermal decomposition of N，Nˊ-dinitromethylenediamine is studied experimentally. The phase relationships between HOMO and LUMO in possible concerted processes are studied with the frontier orbital theory. The process of B-membered cyclic concerted fragmentation is calculated with the CNDO/Ⅱ method. The results of theoretical calculation are in agreement with the experimental results. These results show that the mechanism of the decomposition is basically the concerted process of the 6-membered cyclic fragmentation,

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Jiang Delin、Liu Ziru、Wu Chengyun. On the Mechanism of Thermal Decomposition of N，Nˊ-Dinitrom-e thylenediamine. Acta Armamentarii. 1987, 8(1): 19-29 https://doi.org/10.3969/j.issn.1000-1093.1987.01.003

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